Lithium tritelluride – Wikipedia

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Lithium tritelluride is an intercalary compound of lithium and tellurium with empirical system LiTe
3
. It’s one in all 3 recognized individuals of the Li-Te machine, the others being the uncooked metals and lithium telluride (Li
2
Te
).

LiTe3 used to be first found out in 1969 by means of researchers at america Atomic Power Fee.[1] Analysis into the compound has been essentially pushed by means of the potential for the usage of molten tellurium salts to chill a nuclear reactor.[2][3]

Lithium tritelluride can also be synthesized by means of heating a mix of the fitting stoichiometry. It’s volatile beneath 304 ° C; if left beneath that temperature, it is going to decompose, liberating tellurium vapor.[2][3]

Structurally, lithium tritelluride consists of graphene-like planes of tellurium, organized in parallel with atoms aligned to shape “vertical” columns of tellurium; the lithium ions then shape columns working during the middle of each and every tellurium hexagon.[4]

  1. ^ Foster, M. S.; Johnson, C. E.; Davis, Ok. A.; Peck, J.; Schablaske, R. (1969). (Technical file). USAEC. p. 141. ANL-7575. , as cited in Valentine, Cavin & Yakel 1977.
  2. ^ a b Hitch, B. F.; Toth, L. M.; Brynestad, J. (1978). “The Decomposition Equilibrium of LiTe3“. J. Inorg. Nucl. Chem. Nice Britain: Pergamon Press. 40: 31–34. doi:10.1016/0022-1902(78)80301-7 – by way of Elsevier ScienceDirect. See additionally Cunningham, P. T.; Johnson, S. A.; Cairns, E. J. (March 1973). “Section Equilibria in Chalcogen Techniques III: Lithium-Tellurium”. J. Electrochem. Soc. The Electrochemical Society. 120: 328.
  3. ^ a b Sangster, J.; Pelton, A. D. (1992). “The Li-Te (Lithium-Tellurium) Device”. Phase II: Section Diagram Opinions. Magazine of Section Equilibria. Springer. 13 (3): 300–303. doi:10.1007/BF02667559.
  4. ^ Valentine, Diane Y.; Cavin, O. Burl; Yakel, Harry L. (1977). “At the Crystal Construction of LiTe3“. Acta Cryst. Wiley. B33: 1389–1396. doi:10.1107/S0567740877006141.


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